On Sun, 4 Jun 2017 07:30:02 -0700, BatteryUser
Post by BatteryUserI have several devices that have battery (alkaline AA or AAA) contacts
that regularly get resistive. Opening the device and spinning the
batteries usually solves it but only for a day or so.
What is available to coat the device contacts to prevent the constant
opening and battery spinning ?
These contacts are usually way down inside the device and are not all
that easy to get to.
<https://en.wikipedia.org/wiki/Alkaline_battery#Leaks>
<http://modernsurvivalblog.com/preps/battery-corrosion-why-they-leak-and-how-to-prevent-it/>
What has happened is that the alkaline electrolyte (potassium
hydroxide) attacks the tin or chrome plating on the spring connectors.
The connectors are made from spring steel, plated with copper, nickel
and either chrome or tin (if it needs to be soldered). Oxides of
these metals make for lousy electrical connections.
The problem is that you're not going to improve the connection between
steel (rust) and the battery terminal (stainless steel) with any kind
of "contact enhancer" or magic elixir. Even replating the spring
clips doesn't help if there is a liquid electrolyte or caustic agent
present. The trick is to keep the contacts dry so that there's no
electrolysis possible. That's unlikely with unsealed portable
devices. I've had some luck spot welding small squares of stainless
steel shim stock onto the spring terminals, but that requires total
disassembly of the device, which is not always possible or convenient.
It also hardens the spring steel, causing the spring eventually break.
My experience with various "dielectric greases" and "contact
enhancers" have been dismal. Most do an excellent job of trapping
small amounts of electrolyte in the grease so that it can continue to
do damage. The best I've been able to do is seal the alkaline battery
with thin RTV at the junction of the battery contacts and the case.
That also plugs up the overpressure valve. Fortunately, alkaline
batteries only belch gas at EOL (end of life) which is a tolerable
indication that it's time to replace the cells.
I have a few suggestions on how to minimize the damage caused by
alkaline batteries, but in the end, the only solution is to avoid
using alkaline batteries. I've been switching to LSD (low self
discharge) NiMH cells such as Eneloop, and LiIon where possible. I've
had the older type of NiMH cells leak. However, Eneloops can be made
to leak, usually by overcharging:
<http://www.candlepowerforums.com/vb/showthread.php?180661-NiMH-leakage-Does-it-happen&p=3259769&viewfull=1#post3259769>
None of my LiIon cells have leaked yet. If your device will handle
NiMH cells, do it. If your device can handle LiIon, even better.
Unfortunately, that won't help if your battery contacts have already
had the tin or chrome contact layers removed by corrosion. Replacing
the contacts might be possible. Repairing them with replating is too
much work. Spot welding or soldering some pieces of metal to the
sprint clip is ugly, but does work. Leaving the corroded contact
metal exposed, especially if the battery compartment hasn't been
thoroughly cleaned is guaranteed to recreate your intermittent
connection problem.
Post by BatteryUserQUESTION 2: is there a AA and AAA battery that is less likely to leak
all over and destroy my devices ? Yeah I know, take the batteries out
BUT not always remembered ! So please do not annoy me with that
recommendations.
All the alkalines I've used leak. Some leak in the original
packaging.
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Other alkalines perfer to leak where they can do the most damage:
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Post by BatteryUserI have brand new, never used AA and AAA batteries that leaked. These
are many years before the printed good by date. What total crap.
I have no-name batteries that never leak.
The one that leak are Duracell and Costco brand name batteries.
That's also been my experience. Oddly, Costco Kirkland batteries
didn't leak very much and had a much longer shelf life until after
Costco started putting highly visible expiration dates on their bubble
pack packages. My conspiracy theory is that they did something to
REDUCE the shelf life of their cells.
Post by BatteryUserNow that contacts have been destroyed by leaking batteries, what is the
best procedure to get the contacts working again?
The contacts are deep inside and I cannot take the device apart.
I cannot buy a new device because in some cases they are not available
or are now too expensive to buy.
I tried to answer that under your first question. Basically, you
either provide a better connection by replacing, replating, or
augmenting the contacts, or you'll have continuous bad connections. If
you want a short cut, try welding nickel strips to the terminals of
your battery and bypass the spring contacts completely. It will be
rather awkward having to weld nickel strips onto your alkaline
batteries when they are replaced, but that's the price of not having
to replace the spring contacts. Switching to LSD NiMH will help
reduce the leaks, but won't fix the intermittent connection problem.
--
Jeff Liebermann ***@cruzio.com
150 Felker St #D http://www.LearnByDestroying.com
Santa Cruz CA 95060 http://802.11junk.com
Skype: JeffLiebermann AE6KS 831-336-2558