Discussion:
Heterocyclic compounds with metal hetero atoms
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Peter Percival
2020-01-14 10:33:22 UTC
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Are there heterocyclic compounds with transition metal heteroatoms? I
am aware of heterocyclic compounds with bismuth and tin heteroatoms, but
I'm wondering of there are "more metallic" (so to speak) examples.
Martin Brown
2020-01-14 12:51:59 UTC
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Are there heterocyclic compounds with transition metal heteroatoms?  I
am aware of heterocyclic compounds with bismuth and tin heteroatoms, but
I'm wondering of there are "more metallic" (so to speak) examples.
Will copper do?

https://www.sciencedirect.com/science/article/pii/S0022328X18300718
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Regards,
Martin Brown
Peter Percival
2020-01-14 16:37:26 UTC
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Post by Martin Brown
Are there heterocyclic compounds with transition metal heteroatoms?  I
am aware of heterocyclic compounds with bismuth and tin heteroatoms,
but I'm wondering of there are "more metallic" (so to speak) examples.
Will copper do?
https://www.sciencedirect.com/science/article/pii/S0022328X18300718
Thank you.
Frank
2020-01-15 00:05:44 UTC
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Post by Peter Percival
Post by Martin Brown
Post by Peter Percival
Are there heterocyclic compounds with transition metal heteroatoms?
I am aware of heterocyclic compounds with bismuth and tin
heteroatoms, but I'm wondering of there are "more metallic" (so to
speak) examples.
Will copper do?
https://www.sciencedirect.com/science/article/pii/S0022328X18300718
Thank you.
There are also metal phthalocyanines. Iron and copper are mentioned:

https://en.wikipedia.org/wiki/Phthalocyanine

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